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3D printable tough silicone double networks

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PubDate: Aug 2020

Teams: Facebook,Cornell University

Writers: Thomas J. Wallin, Leif-Erik Simonsen, Wenyang Pan, Kaiyang Wang, Emmanuel Giannelis, Robert F. Shepherd & Yiğit Mengüç

PDF: 3D printable tough silicone double networks

Projecthttps://www.nature.com/articles/s41467-020-17816-y

Abstract

Additive manufacturing permits innovative soft device architectures with micron resolution. The processing requirements, however, restrict the available materials, and joining chemically dissimilar components remains a challenge. Here we report silicone double networks (SilDNs) that participate in orthogonal crosslinking mechanisms—photocurable thiol-ene reactions and condensation reactions—to exercise independent control over both the shape forming process (3D printing) and final mechanical properties. SilDNs simultaneously possess low elastic modulus (E100% < 700kPa) as well as large ultimate strains (dL/L0 up to ~ 400 %), toughnesses (U ~ 1.4 MJ·m−3), and strengths (σ ~ 1 MPa). Importantly, the latent condensation reaction permits cohesive bonding of printed objects to dissimilar substrates with modulus gradients that span more than seven orders of magnitude. We demonstrate soft devices relevant to a broad range of disciplines: models that simulate the geometries and mechanical properties of soft tissue systems and multimaterial assemblies for next generation wearable devices and robotics.

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